Cookie chemistry (2024)

What makes a chocolate chip cookie chewy? Or crisp, or crunchy?

Cookie chemistry.

Cookie chemistry (1)

The interaction between sugar and fat and flour, baking time and temperature – plus a large measure of experimentation done right in your own kitchen – is how to nail your favorite chocolate chip cookie texture.

Let me tell you up front: I'm devoted to simplicity in food prep, and that includes baking. I don't use a cookie cutter, braid bread dough (aside from a basic 3-strand), or decorate cakes.

I put my heart and soul and brain into everything I bake – but I also put those three entities into a zillion other things important to me: like family, friends, counseling women with health issues, and volunteering at various non-profits.

Cookie chemistry (2)

So I'm not fond of trying 87 different takes on a recipe to get it exactly right.

First, I see that as a waste of time; if you can get 95% of the way there in the first three tries, you're good.

And second, having been developing recipes for King Arthur Flour for over 25 years, I know that what comes out of my home kitchen won't be exactly what comes out of yours – even when you follow the recipe exactly as written. Your oven, pans, ingredients, and even your micro-climate and the weather affect what you bake.

So here's the deal: my goal with this post is to show you how to take a basic chocolate chip cookie recipe and give it the texture you prefer: light and crunchy; thin and crisp; or soft and chewy.

More words than you could shake a spatula at have been written about "the perfect chocolate chip cookie." But what is that elusive being, anyway?

Cookie chemistry (3)

Plain and simple, the perfect chocolate chip cookie is the one you love best. So we're going to start with my favorite chocolate chip cookie recipe and, with a few simple tweaks, give you options for potentially turning it into YOUR favorite chocolate chip cookie recipe – no matter which camp your textural preference falls in: crunchy, crisp, or chewy.

Here's your beginning formula. If your favorite cookie is one that's crisp around the edges and softer in the center, stop right here: this is the recipe for you.

2/3 cup light brown sugar, firmly packed
2/3 cup granulated sugar
1/2 cup unsalted butter, right from the fridge, or at room temperature
1/2 cup vegetable shortening
3/4 teaspoon salt
2 teaspoons vanilla extract
1/4 teaspoon almond extract, optional
1 teaspoon vinegar, cider or white
1 teaspoon baking soda
1 large egg
2 cups (8 1/2 ounces) King Arthur Unbleached All-Purpose Flour
2 cups semisweet chocolate chips

Note: For complete directions, see the recipe: Chocolate Chip Cookies. I'm providing you with just the ingredients and some suggested baking temperatures/times here.

Cookie chemistry (4)

How to make crunchy chocolate chip cookies.

1. Substitute 2/3 cup granulated sugar for the brown sugar.

2. Substitute 1/2 cup vegetable shortening for the butter.

3. Bake the cookies for 23 minutes in a preheated 325°F oven.

Cookie chemistry: Crunchiness in a cookie depends on a good balance of fat and dryness. Butter contributes milk solids and water to a cookie, both of which soften it. Brown sugar contributes molasses – again, a softener.

Using lower-moisture sugar (granulated) and fat (vegetable shortening), plus a longer, slower bake than normal, produces light, crunchy cookies.

Cookie chemistry (5)

That said, using a combination of butter and vegetable shortening (as in the original recipe), or even using all butter, will make an acceptably crunchy chocolate chip cookie. It won't be AS crunchy as an all-shortening cookie; but for those who eschew vegetable shortening, it's an option.

Cookie chemistry (6)

How to make crisp chocolate chip cookies.

1. Substitute 2/3 cup granulated sugar for the brown sugar.

2. Substitute 1/2 cup butter for the vegetable shortening.

3. Bake the cookies for 30 minutes in a 325°F oven.

Cookie chemistry (7)

Cookie chemistry: The difference between a crunchy and crisp cookie is thickness; we perceive thicker cookies as crunchy, thinner cookies as crisp.

The melting temperature of butter is lower than that of shortening. As they bake, butter-based cookies start to spread before their structure is set; while those made with shortening set before the shortening reaches its melting point.

The result? In this recipe, cookies made with butter (above, left) are wider, thinner, and crispier than those based on shortening (above, right).

In addition, baking these thin cookies several minutes longer than their shortening-based counterparts transforms their innate crunchiness into crispiness.

Cookie chemistry (8)

How to make soft/chewy chocolate chip cookies.

1. Substitute 1 cup brown sugar for the 2/3 cup brown sugar and 2/3 cup granulated sugar.

2. Substitute 1/2 cup butter for the 1/2 cup vegetable shortening

3. Bake the cookies for 14 minutes in a preheated 325°F oven.

Cookie chemistry: We're taking a 180° turn from our crunchy cookies, substituting higher-moisture brown sugar and butter for their lower-moisture counterparts: granulated sugar and vegetable shortening. That, plus a shortened baking time, yields a cookie that's soft and chewy all the way through.

You'll notice these cookies use less sugar than the original recipe, too. Why is that?

Cookie chemistry (9)

Because the less sugar you use, the less cookies will spread. Above is a mistake I made along the way: one batch of cookies I made had 50% less sugar than it should have. See the difference in spread? (Actually, I liked this 50% less sugar cookie; it tasted plenty sweet, and its butter flavor was more apparent).

Considering I was using all butter (for its extra moistness) in my soft/chewy cookies, I didn't want to use the full ration of sugar as well, fearing the cookies would spread too much.

Cookie chemistry (10)

Some sources call for using bread flour to yield a chewier cookie. I wanted to believe in this, I really did, but the three tests I did showed no difference in chewiness between cookies made with King Arthur Unbleached Bread Flour, and those made with King Arthur Unbleached All-Purpose Flour.

Cookie chemistry (11)

Corn syrup is also recommended by some for extra-chewy cookies. And while I tried adding 2 tablespoons corn syrup to the dough along with the substitutions listed above, I didn't like the result: somewhat glossy, unattractive cookies that had no more chew than their non-corn syrup brethren.

My co-blogger, Susan Reid, says corn syrup is the only way to make "bendy" cookies – but I'll leave that for a future post.

Cookie chemistry (12)

I baked a LOT of chocolate chip cookies over the course of several days in putting together this post. Let me share some additional takeaways with you:

• The chips ratio: My favorite ratio of chocolate chips to cookie is 1 cup chips for every cup of flour in the recipe. This yields a cookie with a generous amount of chips, but not one that seems more gooey chocolate than crunchy cookie.

• Chill out: I discovered awhile ago that letting cookie dough chill for 30 minutes before baking improves cookies' flavor and helps control their spread. I also know that a fully heated oven is critical to cookie success. So make your cookie dough; put it into the fridge; then turn on the oven. Thirty minutes later, your dough will be chilled and your oven fully preheated.

And while we're on the subject – use an in-oven thermometer. The preheating times on ovens are notoriously inaccurate. Only an in-oven thermometer will tell you, for sure, whether your oven's up to temperature and ready to bake.

• Bake a test batch: The perception of crunchy vs. crisp vs. chewy is due somewhat to each person's own personal perception. In addition, all ovens bake slightly differently.

The baking times I give here work for my oven, and yield cookies that I taste as crunchy, crisp, or chewy. To nail down your own baking times, bake just 3 or 4 cookies to start. Let them cool sufficiently for you to see if they're the texture you're after.

Yes, this seems wasteful, letting your hot oven sit empty while cookies are cooling enough to assess their texture. But how much more wasteful is it to make an entire batch of cookies and then, 20 minutes after they're out of the oven, you decide they're not the texture you were looking for?

Cookie chemistry (13)

• Parchment makes a difference: All of my tests were done using parchment-lined, light-colored aluminum baking sheets (including the disastrous first take on chewy cookies pictured above).

Cookies baked on parchment won't spread as much; and their bottoms won't brown (or potentially burn) as quickly. For the complete results of our parchment/no parchment cookie baking tests, see our post, the secret to perfectly browned cookies.

We've arrived at the end of our chocolate chip cookie journey. And I can hear many of you saying, "Yes, but my chocolate chip cookie recipe uses butter and brown sugar and makes the perfect crunchy chocolate chip cookie!"

I have no doubt you can make crisp cookies with butter and brown sugar, and soft cookies with vegetable shortening and white sugar. If you already have your own "perfect" chocolate chip cookie recipe – stick with it! Like so many good things in life, there's more than one way to skin a cat – or bake a chocolate chip cookie.

Cookie chemistry (2024)

FAQs

What is the cookie formula balance? ›

The cake ratio has a 1:1:1:1 ratio of fat to sugar to eggs to flour. The cookie ratio is a 3:2:1 ratio of flour to fat to sugar. Bread has a ratio of 5:3 of flour to water. Just from this, it's clear flour, sugar, fat, eggs, and water are necessary to make any one of these.

What happens at 92 degrees F that causes the dough to start spreading out? ›

The first physical reaction occurs at 92 degrees Fahrenheit. That is the temperature at which the butter starts to melt. The melted butter spreads the cookie out into its flatter shape. At this point, all the ingredients are still the same and there is no change in taste.

What is happening chemically inside the cookie that changes the outcome of that cookie? ›

The Maillard reaction takes place.

The Maillard reaction is a chemical reaction between amino acids and reducing sugars, so along with the caramelizing sugar, proteins in the cookie begin to brown, producing a rich, nutty, toasted flavour. This is the same reaction that occurs in bread and seared steak.

Is cookie male or female? ›

This adorable gender-neutral name has Latin, English, Dutch, and modern roots, all revolving around cooking and baking. The traditional Latin and English meaning of Cookie is "cook," perfect if you want to raise a little future chef.

How old is the first cookie? ›

The Origin of the Cookie

The first cookies are thought to be test cakes bakers used to test the oven temperature. They date back as early as 7th Century A.D. Persia which is now Iran.

What balances flavor in a cookie? ›

Saltiness: Salt plays two very important roles in flavouring a dish. Firstly, it balances against bitterness. Secondly, it enhances most other flavours present in the dish - particularly sweetness. Think about salted caramel - this flavour combination works so well because of the balance created by the salt and sugar.

What chemical compounds are in cookies? ›

  • salt(NaCl)
  • eggs(C720H1134N218S50241)
  • sugar: C12H22O11.
  • Vanilla: C8H8O3.
  • Flour: C 6H10O5.
  • baking soda: NaHCO3.
  • Crisco: soybean oil. palm oil. monoglycerides. diglycerides(C3H6) or (2OH) TBHQ( C10H14O2) citric acid (C6H8O7)

Is 375 too hot for cookies? ›

Cookie temperatures fluctuate, with some recipes as low as 300 degrees Fahrenheit, and a few as high as 425 degrees Fahrenheit, but most recipes land on 375 or 350 to evenly bake the entirety of the cookie.

What makes a cookie flat? ›

If your cookies repeatedly turn out flat, no matter the recipe, chances are your oven is too hot. Here's what's happening. The butter melts super quickly in a too-hot oven before the other ingredients have firmed up into a cookie structure. Therefore, as the butter spreads so does the whole liquidy cookie.

Why bake cookies at 325 degrees? ›

Temperature Makes the Difference

If a thinner slightly crisper cookie is your goal, then consider a lower temperature (325-350 degrees F) and bake longer to allow the dough to spread more before it sets up.

What role does salt play when added to the cookie dough mixture? ›

Salt affects the texture of baked goods by strengthening gluten, which is a protein found in flour. Stronger the gluten, the more elastic the dough or batter, which can lead to better structure and a chewier texture.

How does temperature affect cookie dough? ›

A hot kitchen can make or break a cookie or pie dough. The fat melts making a pie dough crumbly and difficult to work with. Soft butter in the cookie dough impacts how a cookie rises. “Sometimes if the kitchen is hot, we'll put ice packs out on the counter before working with dough,” explains Youngman.

How does refrigeration affect cookie dough? ›

"When your dough is refrigerated, the butter hardens. So when you bake them, they spread less and hold their shape better," adds Epperson. "Which means a better likelihood of a soft, chewy cookie in the center." Chilling the dough creates fluffier cookies with better consistency.

What makes the perfect cookie? ›

The key is to always use top-quality ingredients as they'll result in a better cookie; it really is that simple.
  1. Always use butter.
  2. Choose the right sugar.
  3. Choose the right flour.
  4. Check your flour is in date.
  5. Choose the right kind of chocolate.
  6. Cream the butter and sugar.
  7. Beat in the eggs.
  8. Fold in the flour.

What are the chemistry concepts in baking cookies? ›

Chemistry During Baking

Carbon dioxide gas and water vapor form the bubbles which make cookies rise. Rising doesn't just make cookies taller. It also opens up space to keep the cookie from becoming too dense. Salt slows down the decomposition of baking soda, so the bubbles don't get too big.

What is the cookie model in chemistry? ›

Thomson's model of an atom describes that the electrons are like the chocolate chip cookies which are spread in a sphere of positive charge, which is similar to the rest of the part of the cookie.

What are the properties of a good cookie? ›

Normally the cookie should not be too flat - should be rounded in the middle, should snap if it's crispy or bend and break if it's chewy. If it has nuts, there should be enough of them to have a piece in every bite. The cookies should be big enough to get a good taste of the cookie but not so big that it's a full meal.

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